The Al/MoO3/p-InP metal/insulator/semiconductor
(MIS) and Al/p-InP metal/semiconductor (MS) Schottky Barrier Diodes
(SBDs) have been fabricated to confirm Schottky barrier heights (SBHs)
enhancement by inserting an ultrathin insulator layer between the MS contact.
The current-voltage (I-V) and capacitance-voltage
(C-V) measurements have been performed in the temperature
range of 310–400 K. The modified Richardson plot gives the Richardson constant
of 66.16 and 59.07 A cm− 2 K− 2 for
Al/MoO3/p-InP MIS SBDs and Al/p-InP MS SBDs,
respectively, which are both close to the theoretical value known for
p-InP (60 A cm− 2 K− 2). The SBHs for these two
diodes have decreased with decreasing temperature while the ideality factor
values have increased with decreasing temperature, obeying the barrier height
Gaussian distribution model based on thermionic emission current theory. In
addition, the experimental barrier height shows an obvious enhancement and
ideality factor does not show a considerable increase, verifying that
MoO3 is a good candidate for the interfacial insulator
layer.